CHAPTER 1: REACTION KINETIC (PART 3)

 1.3: Factors Affecting Reaction Rate


The sentences with red color are the main point in explaining factors of concentration, pressure, particle size & temperature affecting reaction rate.



***For temperature & catalyst, they are related with the activation energy

FACTOR - Temperature
If the explanation about general effect of Temperature to the rate of reaction, we use the explanation given above.

If specifically explanation about effect of 2 different Temperature to the rate of reaction, we must refer to MAXWELL - BOLTZMANN DISTRIBUTION CURVE


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Diagram 1: Energy profile of exothermic & endothermic (with & without catalyst)

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CALCULATION USING ARRHENIUS EQUATION


Temperature & Activation energy with presence of catalyst are involved in Arrhenius equation. Thus, we must know the effect when change on Temperature & Activation Energy occur.  
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***R = gas constant (8.314 J/mol K)

Arrhenius equation also can be used as graphical method like integrated rate law in Chapter 1.1: Reaction Rate.

But we use the Arrhenius equation for graphical method using
 ln k = -Ea/R (1/T) + ln A

*** it must obey y = mx + c method in plotting the graph
Therefore, Graph ln k against 1/T will be plotted

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Arrhenius Equation using for calculation


Normally, this equation is used when we have 2 different temperature with different rate constant, k.





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